viernes, 20 de abril de 2007

Mixing height

When an inversion aloft is formed, the atmospheric layer between the earth's surface and and the bottom of the inversion aloft is known as the mixing layer and the distance between the earth's surface and the bottom of inversion aloft is known as the mixing height. Any air pollution plume dispersing beneath an inversion aloft will be limited in vertical mixing to that which occurs beneath the bottom of the inversion aloft (sometimes called the lid). Even if the pollution plume penetrates the inversion, it will not undergo any further significant vertical mixing. As for a pollution plume passing completely through an inversion layer aloft, that rarely occurs unless the pollution plume's source stack is very tall and the inversion lid is fairly low.

Inversion layers

Normally, the air near the Earth's surface is warmer than the air above it because the atmosphere is heated from below as solar radiation warms the earth's surface, which in turn then warms the layer of the atmosphere directly above it. Thus, the atmospheric temperature normally decreases with increasing altitude. However, under certain meteorological conditions, atmospheric layers may form in which the temperature increases with increasing altitude. Such layers are called inversion layers. When such a layer forms at the earth's surface, it is called a surface inversion. When an inversion layer forms at some distance above the earth, it is called an inversion aloft (sometimes referred to as a capping inversion). The air within an inversion aloft is very stable with very little vertical motion. Any rising parcel of air within the inversion soon expands, thereby adiabatically cooling to a lower temperature than the surrounding air and the parcel stops rising. Any sinking parcel soon compresses adiabatically to a higher temperature than the surrounding air and the parcel stops sinking. Thus, any air pollution plume that enters an inversion aloft will undergo very little vertical mixing unless it has sufficient momentum to completely pass through the inversion aloft. That is one reason why an inversion aloft is sometimes called a capping inversion.

Deposition of the pollution plume components to the underlying surface

Dry deposition is the removal of gaseous or particulate material from the pollution plume by contact with the ground surface or vegetation (or even water surfaces) through transfer processes such as absorption and gravitational sedimentation. This may be calculated by means of a deposition velocity, which is related to the resistance of the underlying surface to the transfer.
Wet deposition is the removal of pollution plume components by the action of rain. The wet deposition of radionuclides in a pollution plume by a burst of rain often forms so called hot spots of radioactivity on the underlying surface.

Building effects or downwash

When an air pollution plume flows over nearby buildings or other structures, turbulent eddies are formed in the downwind side of the building. Those eddies cause a plume from a stack source located within about five times the height of a nearby building or structure to be forced down to the ground much sooner than it would if a building or structure were not present. The effect can greatly increase the resulting near-by ground-level pollutant concentrations downstream of the building or structure. If the pollutants in the plume are subject to depletion by contact with the ground (particulates, for example), the concentration increase just downstream of the building or structure will decrease the concentrations further downstream

Buoyant plumes

Plumes which are lighter than air because they are at a higher temperature and lower density than the ambient air which surrounds them, or because they are at about the same temperature as the ambient air but have a lower molecular weight and hence lower density than the ambient air. For example, the emissions from the flue gas stacks of industrial furnaces are buoyant because they are considerably warmer and less dense than the ambient air. As another example, an emission plume of methane gas at ambient air temperatures is buoyant because methane has a lower molecular weight than the ambient air.

Dense gas plumes

Plumes which are heavier than air because they have a higher density than the surrounding ambient air. A plume may have a higher density than air because it has a higher molecular weight than air (for example, a plume of carbon dioxide). A plume may also have a higher density than air if the plume is at a much lower temperature than the air (for example, a plume of evaporated gaseous methane from an accidental release of liquefied natural gas (LNG) may be as cold as -161 °C).
Passive or neutral plumes — Plumes which are neither lighter or heavier than air.

Air pollution dispersion models II

Eulerian model — a Eulerian dispersions model is similar to a Lagrangian model in that it also tracks the movement of a large number of pollution plume parcels as they move from their initial location. The most important difference between the two models is that the Eulerian model uses a fixed three-dimensional Cartesian grid[6] as a frame of reference rather than a moving frame of reference. It is said that an observer of a Eulerian model watches the plume go by.

Dense gas model — Dense gas models are models that simulate the dispersion of dense gas pollution plumes (i.e., pollution plumes that are heavier than air). The three most commonly used dense gas models are:
The DEGADIS model developed by Dr. Jerry Havens and Dr. Tom Spicer at the University of Arkansas under commission by the US Coast Guard and US EPA. [7]
The SLAB model developed by the Lawrence Livermore National Laboratory funded by the US Department of Energy, the US Air Force and the American Petroleum Institute. [8]
The HEGADAS model developed by Shell Oil's research division. [9]

Lagrangian model

A Lagrangian dispersion model mathematically follows pollution plume parcels (also called particles) as the parcels move in the atmosphere and they model the motion of the parcels as a random walk process. The Lagrangian model then calculates the air pollution dispersion by computing the statistics of the trajectories of a large number of the pollution plume parcels. A Lagrangian model uses a moving frame of reference[6] as the parcels move from their initial location. It is said that an observer of a Lagrangian model follows along with the plume.

Gaussian model

The Gaussian model is perhaps the oldest (circa 1936) [3] and perhaps the most commonly used model type. It assumes that the air pollutant dispersion has a Gaussian distribution, meaning that the pollutant distribution has a normal probability distribution. Gaussian models are most often used for predicting the dispersion of continuous, buoyant air pollution plumes originating from ground-level or elevated sources. Gaussian models may also be used for predicting the dispersion of non-continuous air pollution plumes (called puff models). The primary algorithm used in Gaussian modeling is the Generalized Dispersion Equation For A Continuous Point-Source Plume.[4][5]

Box model

The box model is the simplest of the model types.[2] It assumes the airshed (i.e., a given volume of atmospheric air in a geographical region) is in the shape of a box. It also assumes that the air pollutants inside the box are homogeneously distributed and uses that assumption to estimate the average pollutant concentrations anywhere within the airshed. Although useful, this model is very limited in its ability to accurately predict dispersion of air pollutants over an airshed because the assumption of homogeneous pollutant distribution is much too simple.

The Pasquill atmospheric stability classes

The oldest and, for a great many years, the most commonly used method of categorizing the amount of atmospheric turbulence present was the method developed by Pasquill in 1961. [10] He categorized the atmospheric turbulence into six stability classes named A, B, C, D, E and F with class A being the most unstable or most turbulent class, and class F the most stable or least turbulent class. Table 1 lists the six classes and Table 2 provides the meteorological conditions that define each class.

For air dispersion modeling exercises, the conditions of dual stability classes like A – B, B – C and C – D can be considered as B, C and D respectively.

Emission sources II

Sources may be characterized as either stationary or mobile. Flue gas stacks are examples of stationary sources and busses are examples of mobile sources.
Sources may be characterized as either urban or rural because urban areas constitute a so-called heat island and the heat rising from an urban area causes the atmosphere above an urban area to be more turbulent than the atmosphere above a rural area.
Sources may be characterized by their elevation relative to the ground as either surface or ground-level, near surface or elevated sources.
Sources may also be characterized by their time duration:
puff or intermittent: short term sources (for example, many accidental emission releases are short term puffs)
continuous: a long term source (for example, most flue gas stack emissions are continuous)

Emission sources I

The types of air pollutant emission sources are commonly characterized as either point, line, area or volume sources:

Point source — A point source is a single, identifiable source of air pollutant emissions (for example, the emissions from a combustion furnace flue gas stack). Point sources are also characterized as being either elevated or at ground-level. A point source has no geometric dimensions.
Line sources — A line source is one-dimensional source of air pollutant emissions (for example, the emissions from the vehicular traffic on a roadway).
Area source — An area source is a two-dimensional source of diffuse air pollutant emissions (for example, the emissions from a forest fire, a landfill or the evaporated vapors from a large spill of volatile liquid).
Volume source — A volume source is a three-dimensional source of diffuse air pollutant emissions. Essentially, it is an area source with a third (height) dimension (for example, the fugitive gaseous emissions from piping flanges, valves and other equipment at various heights within industrial facilities such as oil refineries and petrochemical plants). Another example would be the emissions from an automobile paint shop with multiple roof vents or multiple open windows.

Air pollution emission plumes II

Dense gas plumes — Plumes which are heavier than air because they have a higher density than the surrounding ambient air. A plume may have a higher density than air because it has a higher molecular weight than air (for example, a plume of carbon dioxide). A plume may also have a higher density than air if the plume is at a much lower temperature than the air (for example, a plume of evaporated gaseous methane from an accidental release of liquefied natural gas (LNG) may be as cold as -161 °C).
Passive or neutral plumes — Plumes which are neither lighter or heavier than air.

Air pollution emission plumes I

There are three primary types of air pollution emission plumes:
Buoyant plumes — Plumes which are lighter than air because they are at a higher temperature and lower density than the ambient air which surrounds them, or because they are at about the same temperature as the ambient air but have a lower molecular weight and hence lower density than the ambient air. For example, the emissions from the flue gas stacks of industrial furnaces are buoyant because they are considerably warmer and less dense than the ambient air. As another example, an emission plume of methane gas at ambient air temperatures is buoyant because methane has a lower molecular weight than the ambient air.

The Briggs plume rise equations II

Briggs divided air pollution plumes into these four general categories:
Cold jet plumes in calm ambient air conditions
Cold jet plumes in windy ambient air conditions
Hot, buoyant plumes in calm ambient air conditions
Hot, buoyant plumes in windy ambient air conditions
Briggs considered the trajectory of cold jet plumes to be dominated by their initial velocity momentum, and the trajectory of hot, buoyant plumes to be dominated by their buoyant momentum to the extent that their initial velocity momentum was relatively unimportant. Although Briggs proposed plume rise equations for each of the above plume categories, it is important to emphasize that "the Briggs equations" which become widely used are those that he proposed for bent-over, hot buoyant plumes.

The Briggs plume rise equations I

The Gaussian air pollutant dispersion equation (discussed above) requires the input of H which is the pollutant plume's centerline height above ground level—and H is the sum of Hs (the actual physical height of the pollutant plume's emission source point) plus ΔH (the plume rise due the plume's buoyancy).

To determine ΔH, many if not most of the air dispersion models developed and used between the late 1960s and the early 2000s used what are known as "the Briggs equations." G.A. Briggs published his first plume rise model observations and comparisons in 1965.[5] In 1968, at a symposium sponsored by CONCAWE (a Dutch organization), he compared many of the plume rise models then available in the literature.[6] In that same year, Briggs also wrote the section of the publication edited by Slade[7] dealing with the comparative analyses of plume rise models. That was followed in 1969 by his classical critical review of the entire plume rise literature,[8] in which he proposed a set of plume rise equations which have became widely known as "the Briggs equations". Subsequently, Briggs modified his 1969 plume rise equations in 1971 and in 1972.[9][10]

The dispersion models require the input of data:

Meteorological conditions such as wind speed and direction, the amount of atmospheric turbulence (as characterized by what is called the "stability class"), the ambient air temperature and the height to the bottom of any inversion aloft that may be present.
Emissions parameters such as source location and height, source vent stack diameter and exit velocity, exit temperature and mass flow rate.
Terrain elevations at the source location and at the receptor location.
The location, height and width of any obstructions (such as buildings or other structures) in the path of the emitted gaseous plume.
Many of the modern, advanced dispersion modeling programs include a pre-processor module for the input of meteorological and other data, and many also include a post-processor module for graphing the output data and/or plotting the area impacted by the air pollutants on maps.

The atmospheric dispersion models are also known as atmospheric diffusion models, air dispersion models, air quality models, and air pollution dispersion models.

Atmospheric dispersion I

Atmospheric dispersion modeling is the mathematical simulation of how air pollutants disperse in the ambient atmosphere. It is performed with computer programs that solve the mathematical equations and algorithms which simulate the pollutant dispersion. The dispersion models are used to estimate or to predict the downwind concentration of air pollutants emitted from sources such as industrial plants and vehicular traffic. Such models are important to governmental agencies tasked with protecting and managing the ambient air quality. The models are typically employed to determine whether existing or proposed new industrial facilities are or will be in compliance with the National Ambient Air Quality Standards (NAAQS) in the United States and other nations. The models also serve to assist in the design of effective control strategies to reduce emissions of harmful air pollutants.

Reduction efforts

There are many available air pollution control technologies and urban planning strategies available to reduce air pollution; however, worldwide costs of addressing the issue are high.[citation needed] Enforced air quality standards, like the Clean Air Act in the United States, have reduced the presence of some pollutants.

Many countries have programs to or are debating how to reduce dependence on fossil fuels for energy production and shift toward renewable energy technologies or nuclear power plants.

Efforts to reduce pollution from mobile sources includes primary regulation (many developing countries have permissive regulations), expanding regulation to new sources (such as cruise and transport ships, farm equipment, and small gas-powered equipment such as lawn trimmers, chainsaws, and snowmobiles), increased fuel efficiency (such as through the use of hybrid vehicles), conversion to cleaner fuels (such as bioethanol, biodiesel), or conversion to electric vehicles with renewable energy sources (batteries or clean fuel such as hydrogen being used for transport and storage).

Indoor air quality II

Though its use has now been banned in many countries, the extensive use of asbestos in industrial and domestic environments in the past has left a potentially very dangerous material in many localities. Asbestosis is a chronic inflammatory medical condition affecting the tissue of the lungs. It occurs after long-term, heavy exposure to asbestos, e.g. in mining or in the installation or removal of asbestos-containing materials from structures. Sufferers have severe dyspnea (shortness of breath) and are at an increased risk regarding several different types of lung cancer. As clear explanations are not always stressed in non-technical literature, care should be taken to distinguish between several forms of relevant diseases. According to the World Health Organisation (WHO), these may defined as; asbestosis, lung cancer, and mesothelioma (generally a very rare form of cancer, when more widespread it is almost always associated with prolonged exposure to asbestos).

Biological sources of air pollution are also found indoors, as gases and airborne particulates. Pets produce dander, people produce dust from minute skin flakes, dust mites in bedding, carpeting and furniture produce enzymes and micron-sized fecal droppings, inhabitants emit methane, mold forms in walls and generates mycotoxins and spores, air conditioning systems can incubate Legionnaires' disease and mold, toilets can emit feces-tainted mists [1], and houseplants, soil and surrounding gardens can produce pollen, dust, and mold. Indoors, the lack of air circulation allows these airborne pollutants to accumulate more than they would otherwise occur in nature.

Indoor air quality I

The lack of ventilation indoors concentrates air pollution where people have greatest exposure times. Radon (Rn) gas, a carcinogen, is exuded from the Earth in certain locations and trapped inside houses. Researchers have found that radon gas is responsible for over 1,800 deaths annually in the United Kingdom.[citation needed] Building materials including carpeting and plywood emit formaldehyde (H2CO) gas. Paint and solvents give off volatile organic compounds (VOCs) as they dry. Lead paint can degenerate into dust and be inhaled. Intentional air pollution is introduced with the use of air fresheners, incense, and other scented items. Controlled wood fires in stoves and fireplaces can add significant amounts of smoke particulates into the air, inside and out. Indoor air pollution may arise from such mundane sources as shower water mist containing arsenic or manganese, both of which are damaging to inhale. The arsenic (As3+) can be trapped with a shower nozzle filter.

Indoor pollution fatalities may be caused by using pesticides and other chemical sprays indoors without proper ventilation, and many homes have been destroyed by accidental pesticide explosions.[citation needed]

Carbon monoxide (CO) poisoning is a quick and silent killer, often caused by faulty vents and chimneys, or by the burning of charcoal indoors. 56,000 Americans died from CO in the period 1979-1988.[citation needed] Chronic carbon monoxide poisoning can result even from poorly adjusted pilot lights. Smoke inhalation is a common cause of death in victims of house fires. Traps are built into all domestic plumbing to keep deadly sewer gas, hydrogen sulfide, out of interiors. Clothing emits tetrachloroethylene, or other dry cleaning fluids, for days after dry cleaning.

Pollutants II

Primary pollutants produced by human activity include:

oxides of sulfur, nitrogen and carbon
organic compounds, such as hydrocarbons (fuel vapours and solvents)
particulate matter, such as smoke and dust
metal oxides, especially those of lead, cadmium, copper and iron
chlorofluorocarbons (CFCs)
hazardous air pollutants (HAP)
persistent organic pollutants (POPs)
odours
Secondary pollutants include some particles formed from gaseous primary pollutants and compounds in photochemical smog, such as nitrogen dioxide, ground level ozone and peroxyacetyl nitrate (PAN).

Pollutants I

There are many substances in the air which may impair the health of plants and animals (including humans), or reduce visibility. These arise both from natural processes and human activity. Substances not naturally found in the air or at greater concentrations or in different locations from usual are referred to as 'pollutants'.

Pollutants can be classified as either primary or secondary. Primary pollutants are substances directly produced by a process, such as ash from a volcanic eruption or the carbon monoxide gas from a motor vehicle exhaust.

Secondary pollutants are not emitted. Rather, they form in the air when primary pollutants react or interact. An important example of a secondary pollutant is ground level ozone - one of the many secondary pollutants that make up photochemical smog.

Note that some pollutants may be both primary and secondary: that is, they are both emitted directly and formed from other primary pollutants.

Air pollution

Air pollution is a chemical, physical (e.g. particulate matter), or biological agent that modifies the natural characteristics of the atmosphere. The atmosphere is a complex, dynamic natural gaseous system that is essential to support life on planet Earth. Stratospheric ozone depletion due to air pollution has long been recognized as a threat to human health as well as to the Earth's ecosystems.

Worldwide air pollution is responsible for large numbers of deaths and cases of respiratory disease. Enforced air quality standards, like the Clean Air Act in the United States, have reduced the presence of some pollutants. While major stationary sources are often identified with air pollution, the greatest source of emissions is actually made up by mobile sources, mainly the automobiles. Gases such as carbon dioxide, which contribute to global warming, have recently gained recognition as pollutants by some scientists. Others recognize the gas as being essential to life, and therefore incapable of being classed as a pollutant.